84
ANALYTICAL EXPERIMENTS
be diffolved in water, the whole of it must be capable of dissolution
in that fluid.
This proposition had, at that time, less appearance of probability
than any of the former. It was universally believed that lime was
only partially foluble in water ; and different opinions were entertained -
of the proportion of it that could be diffolved. Dr. Alston contended ¬
that a fourth part of it, or perhaps a little more, might be disfolved, ¬
provided a very large quantity of water was employed; such
as 500 times the weight of the lime. But the general opinion was
that a much smaller portion of it only was soluble and active. The
question had never been decided by an accurate experiment.
I therefore chofe a bit of chalk, which, when heated to a sufficient
degree in a crucible, afforded a little mass of perfect quicklime, weighing ¬
eight grains. This little maſs was thrown, while yet warm, into
a small quantity of warm distilled water in a phial, in which it was
soon flaked, and formed a white mixture like milk. This mixture
was immediately poured into a larger glafs vessel, in which I had
eighteen ounces of distilled water.
While the milky mixture was diffused through the water, the lime
was ſeen to difsolve almoft entirely; nothing remained undissolved
but a very light fæculency, which was almoſt transparent, or only
like thin clouds in the liquor. This fæculency, when it was allowed
to subside, and was collected with the greatest care on a small filtre
and dried, weighed only the third part of a grain. In some repetitions ¬
of the experiment it weighed lefs, and in others a little more.
Being examined by putting it on a plate of glass, and adding a drop
of diluted nitric acid, it was diffolved in part, with effervescence, but a
part of it remained undiffolved, which was ochre of iron. It appeared, ¬
therefore, to be composed of a minute portion of the lime, which
had fomehow recovered fixed air, and of ochre of iron, and perhaps a
little clay, which are well known to be often present, in smnall quantity,
in chalk.