344
Book V.
Putrefac
tion.
Action ot
sulphuric
acid,
Nitric acid,
ANIMAL SUBSTANCES.
When the solution of urea in water is kept in a boil
ing heat, and new water is added as it evaporates, the
urea is gradually decomposed, a very
great quantity of
carbonat of ammonia is disengaged, and at the same
time acetous acid is formed, and some charcoal precipi
tates*.
When a solution of urea in water is left to itself for
some time, it is gradually decomposed. A froth col
lects on its surface ; air bubbles are emitted which have
a strong disagreeable smell, in which ammonia and ace
tous acid are distinguishable. The liquid contains a
quantity of acetous acid. The decomposition is much
more rapid if a little gelatine be added to the solution.
In that case more ammonia is disengaged, and the pro
portion of acetous acid is not so greatf.
When the solution of urea is mixed with one-fourth
of its weight of diluted sulphuric acid, no effervescence
takes place ; but, on the application of heat, a quantity
of oil appears on the surface, which concretes upon
cooling ; the liquid which comes over into the receiver
contains acetous acid, and a quantity of sulphat of am
monia remains in the retort dissolved in the undistil
led mass. By repeated distillations, the whole of the
urea is converted into acetous acid and ammoniaf.
When nitric acid is poured upon crystallized urea, a
violent effervescence takes place, the mixture frothes,
assumes the form of a dark red liquid, great quantities
of nitrous gas, azotic gas, and carbonic acid gas, are
disengaged. When the effervescence is over, there re
mains only a concrete white matter, with some drops of
reddish liquid. When heat is applied to this residuum,
F Ann. de Chim. xxxi. 96.
Ibid.
t Ibid. p. 104.