WATERS.
397
Chap.IV.
nine, if muriat of iron be included. The most common
by far is muriat of soda.
r. Alkaline.
1. Muriat of soda and of potass may be detected by
the following method : Separate the sulphuric acid by
alcohol and nitrat of barytes. Decompose the earthy
nitrats and muriats by adding sulphuric acid. Expel
the excess of muriatic and nitric acids by heat. Sepa
rate the sulphats thus formed by alcohol and barytic
water. The water thus purified can contain nothing
but alkaline nitrats and muriats. If it forms a precipi
tate with acetite of silver, we may conclude that it con
tains muriat of soda or of potass. To ascertain which,
evaporate the iiquid thus precipitated to dryness; dis
solve the acetite in alcohol. Evaporate to dryness. The
salt will deliquesce if it be acetite of potass, but effloresce
if it be acetite of soda.
2. Muriat of barytes may be detected by sulphuric 2. Barytic.
acid, as it is the only barytic salt hitherto found in
waters.
3. Calcare
3. Muriat of lime may be detected by the following
ous.
method: Free the water of sulphat of lime and other
sulphats, by evaporating it to a few ounces, mixing it
with spirit of wine, and adding last of all nitrat of
barytes as long as any precipitate appears. Filter off the
water, evaporate to dryness, treat the dry mass with
alcohol. Evaporate the alcohol to dryness and dissolve
the residuum in water. If this solution gives a precipi
tate with acetite of silver and oxalic acid, it may con
tain muriat of lime. It must contain it in that case,
if, after being treated with carbonat of lime, it gives no
precipitate with ammonia. If it does, separate the lime
by means of oxalic acid, filter and distil with a gentle
heat. If the liquid in the receiver gives a precipitate with
nitrat of silver, muriat of lime existed in the water.