Book II.
Division II
How chan
ged inte
sulphat.
SALTS OF
for some time, or by pouring into it nitric acid, and ap
plying heat *.
This salt has a red colour. It does not afford crystals;
and when evaporated to dryness; soon attracts moisture,
and becomes again liquid. It is exceedingly soluble in
water, and also in alcohol. By this last liquid it may
be separated from the sulphat of iron, with which it is
always mixed in the vitriol of commerce. When ex
posed to the air, it gradually deposites red oxide, or ra
ther oxy sulphat with excess of base.
A great number of substances have the property of
depriving this salt of its excess of oxygen, and of con
verting it into sulphat of iron. This is the case
with iron. When the solution of oxy-sulphat is mix
ed with iron-filings, and kept for some time in a
well-covered vessel, part of the iron is dissolved by
abstracting the second dose of oxygen from the oxide,
and the whole is converted into sulphat. The same
change is produced by tin, and probably also by all
the salts of tin which contain that metal combined
with a minimum of oxygen. Sulphurated hydrogen
produces that change instantaneously when made to
pass through a solution of oxy-sulphat *. That gas has
the property of reducing the oxides of iron to a mini
mum of oxygen ; but it does not bring them to thé me
tallic state. Hence the reason that it does not preci
pitate iron from its solution in acids.
On the other hand, all those bodies which part with
oxygen very readily, convert the sulphat of iron into
* During this change a quantity of ammonia is also formed. Hence
not only the nitric acid but some water also is decomposed.—See Davy's
Researches, p. 157.
Proust, Ann. de Cbim. xxii. 23.