SILVER.
precipitated in the state of a white powder when phos
phorie acid is poured into liquid nitrat of silver. It is
insoluble in water, but soluble in an excess of phos
phoric acid. When heated strongly in a crucible, a
little phosphorus comes over, and phosphuret of silver
remains in the retort *.
Sp.6. Fluat of Siber.
FLUORIC ACID does not attack silver ; but its oxide
is partly dissolved by that acid, and partly forms with
it an insoluble salt †. This acid precipitates the fluat
of silver from the liquid nitrat in the form of a white
heavy powder, which is supposed by some to resemble
the appearance of muriat of silver. This salt is decom
posed by the sulphuric acid.
Sp. 1. Borat g Siber.
BORACIC ACID has no action on silver whatever ; but
the borat may be formed by pouring a solution of bo
rax into liquid nitrat of silver. The salt falls to the
bottom in the form of an insoluble white powder, which
has not been examined.
Sp. 8. Carbonat of Silver.
CARBONIC ACID has no action whatever upon silver;
but it is absorbed readily by the oxide of that metal.
The carbonat may be obtained by precipitating silver
from its acid solutions by means of a carbonated alkali.
A white insoluble powder is obtained, which is carbo
nat of silver. This salt becomes black when exposed
to the light; and, when heated, the acid is driven off,
* Fourcroy, vi. 340.
Scheele, i. 32,
G g3
469
Chap. II.