GOLD.
sened with water: when perfectly dry, it is not alter
ed. This is not peculiar to the action of combustibles:
on metallic salts, it holds also, as we shall see afterwards,
with respect to the metals. But it is by no means easy
to see what makes water so indispensably necessary. It
is not, as is commonly supposed, in order to secure the
fluidity of the mixture : for Mrs Fulhame has shewn
that ether, though a liquid, has no effect in reducing
gold unless water be present. She accounts very inge
niously for the phenomena, by supposing that the wa
ter is decomposed. The combustible combines with its
oxygen, while its hydrogen combines with the oxygen
of the gold, and reproduces water. This theory accounts
very well for the phenomena; but it would require some
direct proof to establish it completely.
The greater number of the metals, when plunged in
to the solution of muriat of gold, occasion a precipitate
either of gold in the metallic state, or of its purple ox
ide; while at the same time a portion of the precipita
ting metal is oxidated and dissolved by the acid. Zinc,
iron, bismuth, copper, mercury, precipitate it in the
metallic state. Lead, silver, and tin, precipitate it in
the state of purple oxide. The sulphat of iron preci
pitates it in the metallic state, and is at the same time
converted into the oxy-sulphat by the oxygen which it
has absorbed : whereas the oxy-sulphat of iron produ
ces no effect at all. The same thing happens with tin.
The muriat of that metal precipitates the gold in the
state of purple oxide, combined with oxide of tin ; a
precipitate well known by the name of precipitate of
Cassius, and used to give a red colour to porcelain and
glass: But the oxy-muriat of tin, which is already at
Ffa
455
Chap. III.
And by
metals,