88
Book II.
Does not
deserve the
name of
acid.
Nungsras.
ACIDS.
acid dissolves the lime, and the ammonia combines with
the tungstic acid. The ammoniacal solution, when satu
rated with nitric or muriatic acid, deposites a white
powder, which is the tungstic acid of Scheele.
This powder has an acid taste, it reddens vegetable
blues, and is soluble in 20 parts of boiling water. The
De Luyarts have demonstrated, that this pretended acid
is a compound of yellow oxide of tungsten, the alkali
employed to dissolve it, and the acid used to precipitate
it. Thus, when prepared according to the above de
scribed process, it is a compound of yellow oxide, am
monia, and nitric acid. Their conclusions have been
more lately confirmed by the experiments of Vauque
lin and Hecht. This substance must therefore be erased
from the class of acids, and placed among the salts.
The real acid of tungsten is a yellow powder; the
method of procuring which, and its properties, have
been already described under the denomination of Tel
low Oxide of Tungsten*. It ought rather, as Vauque
lin and Hecht have properly remarked, to be classed
among the oxides than the acids ; for it is insoluble in
water, tasteless, and has no effect on vegetable blues.
It agrees with the acids indeed in the property of com
bining with alkalies and earths, and perhaps also with
some metallic oxides, and forming with them salts
which have been denominated tungstats; but several
other metallic oxides, those of lead, silver, and gold,
for instance, possess the same property. These oxides
therefore may be called acids with as much propriety
as the yellow oxide of tungsten.
F Vol. L.p.215.