440
Book II.
Action on
barytes.
Strontian.
Lime.
EARTHS.
with phosphorus, at least no person has hitherto been
able to form a phosphuret of magnesia.
There is an affinity between sulphur and magnesia.
The sulphuret may be formed by exposing a mixture
of two parts of magnesia and one part of sulphur to a
gentle heat in a crucible. The result is a yellow pow
der, slightly agglutinated, which emits very little sul
phurated hydrogen gas when thrown into water. A
moderate heat is sufficient to drive off the sulphur *.
It has no action upon the metals ; nor does it com
bine, as far as is known at present, with the metallic
oxides, unless some intermediate substance be present.
Neither does magnesia combine with the alkalies.
There seems to be little affinity between magnesia
and barytes ; at least no mixture of the two earths is
fusible in the strongest heat which it has been possible
to applyf. Muriat of magnesia, indeed, and muriat of
barytes, occasion a precipitate ; but the nature of this
precipitate has not been examinedf.
Mr Kirwan has shown that there is but little affinity
between strontian and magnesia. They do not melt
when exposed to a strong heat, at least when the stron
tian exceeds or equals the lime .
Equal parts of lime and magnesia, mixed together,
and exposed by Lavoisier to a very violent heat, did not
melt; neither did they melt when Mr Kirwan placed
them in the temperature of 150° Wedgewood. —The
following Table, drawn up by Mr Kirwan from his
own experiments, shews the effect of heat on these two
earths mixed together in different proportions.
t Lavoisier, Mem. Par. 1782.
F Fourcroy, i. 165.
Irisb Tranc. v. 246, 247.
Morveau, Ann, de Chim. xxxi. 253.