443
ACIDS.
Malt Vinegar.
In this country vinegar is usually made from malt. By
mashing with hot water, 100 gallons of wort are extracted,
in less than two hours, from six bushels of malt. When the
liquor has fallen to the temperature of 75° Fahr., four gal
lons of yeast are added. After thirty-six hours it is racked
off into casks, which are laid on their sides, and exposed,
with their bung holes loosely covered, to the influence of
the sun in summer; but in winter they are arranged in a
room heated by stoves. In three months this vinegar is
ready for the manufacture of sugar of lead.
To make vinegar for domestic use, however, the process
is somewhat different. The above liquor is racked off into
pairs of casks placed upright, having a false bottom pierced
with holes fixed a foot from their bottoms. On this a
considerable quantity of rape, or the refuse from the makers
of British wine, or otherwise a quantity of low-priced raisins
is laid. The liquor is pumped into the other barrel every
twenty-four hours, in which time it has begun to grow
warm. Sometimes, indeed, the vinegar is fully fermented
without the rape, which is added, towards the end, to
communicate flavour.
Vinegar is made at Ghent, in Flanders, from beer; in
which the following proportions of grain are found to be
most advantageous : 1880 pounds of malted barley ; 700 of
wheat; and 500 of buck wheat. These grains are ground,
mixed and boiled, along with twenty-seven barrels of river
water, for three hours; eighteen barrels of good beer for
vinegar are obtained. By a subsequent decoction, more
fermentable liquid is extracted, which is mixed with the
former. The whole brewing yields about 750 gallons, Eng
lish measure, of vinegar.
Common vinegar has, sometimes, sulpnuric acid fraudu
lently mixed with it, to give strength. This adulteration
may be detected by the addition of a little chalk. With
pure vinegar, lime forms a limpid solution ; but with sul
phuric acid, a white insoluble sulphate. Muriate of barytes
is a still nicer test. Vinegars are allowed, by the English
laws, to contain a little sulphuric acid, but the quantity is
frequently exceeded.
Copper is discovered in vinegar by adding more ammonia
water than is necessary to saturate it, as a fine blue colour
is produced ; and lead is discovered by sulphate of soda,
hydro-sulphurets, sulphuretted hydrogen, and gallic acid,