413
ACIDS.
forms us that sulphuric acid was manufactured in France,
forty years ago, by burning sulphur with saltpetre, but at
present, by reverting to the old process of burning sulphur
alone.
The process with saltpetre consisted in shoving into a
chamber lined with lead, containing from five to ten thou
sand cubic feet, an iron carriage, carrying a cast-iron dish
full of burning sulphur, the combustion of which was pro
moted by a portion of saltpetre, amounting to ten, fifteen,
or even twenty in the hundred. Some manufacturers in
jected a shower of water by a forcing pump, through a rose.
When it was supposed that the combustion was completed
and that the acid formed had been condensed by the water,
the door was opened at which the chariot had been intro
duced, it was taken out to clear away.the residuum, again
loaded, and the operation repeated.
The acid obtained was evaporated’and concentrated in
leaden boilers •50° to Baumé, and then concentrated in
glass retorts, ranged, as many as twenty or thirty, in a sand
bath, and all heated by the same fire.
The result of all these proceedings was to obtain from 150
to 200 parts of sulphuric acid, of the specific gravity of 1,845,
or 66° of Baumé for every hundred of sulphur employed,
and very often the operation entirely failed. The residuum
was at first flung away, although it contained nearly one
third of the sulphur used, and much sulphate of potasse ;
but afterwards it was sold to the alum-works, and used in
that manufactory.
The putting in the sulphur by a carriage was then done
away, and an immoveable furnace constructed under the
chamber. The dish in which the sulphur was burnt was
heated by fire, and the mixture of one hundred parts sul
phur to ten or twelve saltpetre was introduced from time to
time, by means of a small door for this purpose. A hole,
two inches above the level of the sulphur, permitted a con
stant ingress of air, and a chimney at the other extremity
created a draught which carried off the uncondensed gases.
In damp weather, particularly, they fell all around, and de
stroyed all vegetation in a pretty extensive circle.
Some acid was always left in the chamber ; and as more
was formed, a quantity was drawn off and concentrated in
glass vessels. This method of concentrating the acid is
still generally employed, except that, instead of several glass
retorts, a single platinum alembic is now in use. By this