METALS.
741
The oxide thus obtained, is to be put into a crucible, and
melted in a brisk fire, without any addition ; it generally
forms a brown transparent glass. If the antimony has been
calcined too much, it is rather hard to melt ; some chemists
in this case, throw a little common antimony into the crucible ¬
; but this addition gives the glass a darker colour than
if pure.
It is used to prepare tartar emetic.
Some years ago a druggist, being distressed and in the King’s Bench
Prison, made a quantity of glass of lead, coloured it to imitate glass of
antimony, and sold it for that article before the fraud was discovered.
Some of this glass still remains in the apothecaries' shops, to whom it
was sold.
Glass of antimony varies in its ingredients, according to the quantity
of silica that it extracts from the crucible.
Crocus Metallorum.
This is made by calcining common antimony until it acquires only a
dull grey colour, and then melting it in a crucible.
It is used to make emetic tartar.
Emetic Tartar.
The old process for making this double salt, was to mix
one pound of crocus metallorum with a pound of cream of
tartar, boil the mixed powder in a gallon of water for an
hour or two, filter, evaporate to a pellicle, and set it by to
crystallize; the mother water is again evaporated, until it
ceases to yield crystals.
But since glass of antimony has been manufactured on a
large scale, and thus may be bought cheaper than the crocus -
can be made, it has been used in preference.
A number of other processes, some of them very complicated, ¬
have been given for making this salt; but their use
have been confined to their inventors, as all the wholesale
makers of emetic tartar use one or other of the above
methods.
Emetic tartar is at present the most generally used antimonial medicine, ¬
and its exhibition may be managed so as to produce either sweating, ¬
purging, or vomiting,
Berzelius calls this salt tartras kalico stibicus, ôr 3 K: T -2Aq2+
—» Aq’, and thus makes its atomic weight 28,235,830. Dr. T.
4 Sb:1
Thomson thinks it should be called ditartrate of potash and antimony,
considers its composition to be T — Sb; + T— K: Sb; + 2 Aq, and
its weight, 44,250. Gay-Lussac thinks the cream of tartar performs in
this and similar salts, the part of a simple acid.
Kermes Mineral.
The best process for making this medical article, much
used by the Continental physicians, is to boil one pound of