SULPHURIC.
grains of distilled water, have the same specific gravity
at the same temperature ; from whence it follows, that
the proportion of salt in each was equal. But in the
last solution the quantity of salt was — of the whole;
23.6
28994
therefore the quantity of salt in the first was
23.6
— 159.52 grs. Now of this weight 86 grains were
alkali; the remainder therefore, which amounts to
70.52 grains, must be acid. But the quantity of acid
employed was 79 grains; of this there were 8½ grains,
which did not enter into the combination, and which
must have been pure water : 79 parts of acid, of the
specific gravity 2, therefore contain at least 8, 5 parts
of water ; and consequently 1o0 parts of it contain
10.75 parts of water. It only remains now to consider
how much water sulphat of potass contains. Mr Kir
wan thinks it contains none, because it loses no weight
in any degree of heat below ignition, and even when,
exposed to a red heat for half an hour it hardly loses a
grain. This is certainly sufficient to prove, at least,
that it contains very little water; and consequently we
may conclude, with Mr Kirwan, that 100 parts of sul
phuric acid, of the specific gravity 2.000, are composed
pretty nearly of 89.25 of pure acid and 10.75 of water.
Since there is such a strong affinity between sulphu
ric acid and water, and since the density of the mixture
is different from the mean density of the ingredients, it
becomes a problem of the greatest importance to deter
mine how much of the strongest sulphuric acid that can
be prepared exists in any given quantity of sulphuric
acid of inferior specific gravity, and which consequently
consists of a determinate quantity of this strong acid di
luted with water.
13
Chap.NV.